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Konstantinos Kavallieratos

Konstantinos Kavallieratos

Associate Professor, Florida International University

Phone: (305) 348-6034

Fax: (305) 348-3772

11200 SW 8th St. CP 326,
Miami, FL 33199.

http://www2.fiu.edu/~kavallie/

Education:

Ph. D., Chemistry, Yale University, 1998 (June)

Research Interests:

  • Hydrogen bonding in molecular recognition and self-assembly.
  • Applications to organometallic and coordination chemistry, organic synthesis, catalysis and separation technology.
  • Crystal engineering and supramolecular arrays.
  • Sensors and novel materials for biomimetic and environmental applications.

Publications List:

20. R. J. Alvarado, J. M. Rosenberg, A. Andreu, J. C. Bryan, W.-Z. Chen, T. Ren, K. Kavallieratos. Structural insights into the coordination and extraction of Pb(II) by disulfonamide ion exchangers. Inorg. Chem., 2005, in press.

19. K. Kavallieratos, A. J. Sabucedo, A. T. Pau, J. M. Rodriguez. APCI-MS characterization of anionic adducts. J. Am. Soc. Mass Spectrom. 2005, 16, 1377 .

18. K. Kavallieratos, J. M. Rosenberg, W. Chen, T. Ren, Fluorescent sensing and selective extraction of Pb(II) by a dansylamide ion-exchanger, J. Am. Chem. Soc. 2005, 127, 6514.

17. K. Kavallieratos, J. M. Rosenberg, J. C. Bryan, Pb(II) coordination and synergistic extraction by combinations of disulfonamide ion-exchangers and 2,2'-bipyridine, Inorg. Chem., 2005, 44, 2573.

16. J. C. Bryan, J. M. Rosenberg, K. Kavallieratos, 1,2-bis(phenyl)-phenylenediamine, Acta Crystallogr. E. 2005, E61, o-396.

15. K. Kavallieratos, J. C. Bryan, R. A. Sachleben, G. J. Van Berkel, , O.E. Espetia, M. A. Kelly, A. M. Danby, K. Bowman-James, B. A. Moyer Dual-Host combinations:Using Tripodal Amides to Enhance Cesium Nitrate Extraction by Crown Ethers. In Fundamentals and Applications of Anion Separations; B. A. Moyer and R. Singh, Eds.; Kluwer: New York, 2004, pp 125-150.

14. C. T. Eagle, K. Kavallieratos, J. C. BryanNon-preorganized neutral acyclic anion receptors; structural investigations of N,N'- diphenyl-1,3-benzenedisulfonamide and N,N'-bis(4-t-butylphenyl)-1,3- benzenedisulfonamide.J. Chem. Crys. 2002, 32, 165.

13. B. A. Moyer, P. V. Bonnesen, L. H. Delmau, T. J. Haverlock, K. Kavallieratos, T. G. Levitskaia, Toward recognition of the anion in the extraction of alkali metal salts by crown ethers and calixarenes. Int. Solv. Extr. Conf., 2002, 299-306.

12. K. Kavallieratos, B. A. MoyerSpectacular Cs extraction by the use of a potent dual-host combination.Chem. Commun. 2001, 1620.

11. W. Yao, K. Kavallieratos, S. R. de Gala, R. H. CrabtreeTripyrimidylamine. A new thermally robust ligand for Ruthenium.Inorg. Chim. Acta 2000, 311, 45.

10. K. Kavallieratos, A. M. Danby, G. J. Van Berkel, M. A. Kelly, R. A. Sachleben, B. A. Moyer,K. Bowman-JamesTriamide derivatives of tris(2-aminoethyl)amine (tren) as Cesium nitrate co-extractants.Anal. Chem. 2000, 72, 5258.

9. J. C. Bryan, K. Kavallieratos, R. A. SachlebenUnusual ligand coordination for Cesium.Inorg. Chem. 2000, 39, 1568.

8. K. Kavallieratos, R. A. Sachleben, G. J. Van Berkel, B. A. MoyerNovel dual-host approach in ion-pair extraction.A simple tripodal anion hostfacilitates Cesium Nitrate transfer to 1,2-dichloroethane by a large crown ether.Chem. Commun. 2000, 187.

7. A. Castellanos, J. A. Ayllon, S. Sabo-Etienne, B. Donnadieu, B. Chaudret, W. Yao,K. Kavallieratos, R. H. CrabtreeFast H NMR relaxation from hydride-proton interactions in some Ru hydrides.Comptes Rendus Acad. Sci. (Paris) Ser. IIc1999, 2, 359. (Invited for H. Poiblanc issue).

6. P. Desmurs, K. Kavallieratos, W. Yao, R. H. CrabtreeIntermolecular Re-H...H-N and Re-H...base hydrogen bonding estimated in solution by a UV-VIS spectroscopic method.New J. Chem. 1999, 23, 1111.
5. K. Kavallieratos, C. M. Bertao, R. H. Crabtree Hydrogen bonding in anion recognition. A family of versatile, non-preorganized,neutral and acyclic receptors.J. Org. Chem. 1999, 64, 1675.

4. K. Kavallieratos, R. H. CrabtreeCatalysis of aldehyde imination by hydrogen bonding with a simple receptor.Chem. Commun. 1999, 2109.

3. K. Kavallieratos, S. Hwang, R. H. Crabtree Aminoferrocene derivatives in chloride recognition and electrochemical sensing.Inorg. Chem. 1999, 38, 5184.

2. B. P. Patel, K. Kavallieratos, R. H. Crabtree Effects of dihydrogen bonding on fluxionality in ReH5(PPh3)2L.J. Orgmet. Chem. 1997, 28, 205.
1. K. Kavallieratos, S. R. de Gala, D. J. Austin, R. H. CrabtreeA readily available non-preorganized neutral acyclic halide receptor with anunusual nonplanar binding conformation.J. Am. Chem. Soc. 1997, 119, 2325.